The value of Faraday’s constant (F) is:
F=96485 C/molF = 96485 \text{ C/mol}
What is Faraday’s Constant?
Faraday’s constant represents the electric charge carried by one mole of electrons. It is the product of:
F=NA×eF = N_A \times e
Where:
- NA=6.022×1023N_A = 6.022 \times 10^{23} (Avogadro’s number) – number of particles per mole
- e=1.602×10−19e = 1.602 \times 10^{-19} Coulombs – charge of one electron
Multiplying these values:
F=(6.022×1023)×(1.602×10−19)F = (6.022 \times 10^{23}) \times (1.602 \times 10^{-19}) F≈96485 C/molF \approx 96485 \text{ C/mol}
Common Approximations:
- 96485 C/mol (exact value)
- 96500 C/mol (rounded for quick calculations)
Where is Faraday’s Constant Used?
- Electrolysis Calculations
- Used in Faraday’s laws of electrolysis to determine the amount of substance deposited or dissolved during electrolysis.
m=QF×Mnm = \frac{Q}{F} \times \frac{M}{n}Where:
- mm = Mass deposited (g)
- QQ = Charge passed (Coulombs)
- FF = 96485 C/mol
- MM = Molar mass of substance
- nn = Number of electrons transferred
- Nernst Equation
- Helps in calculating electrode potential under non-standard conditions:
E=E∘−RTnFlnQE = E^\circ – \frac{RT}{nF} \ln Q
- Gibbs Free Energy and Electrochemical Cells
- Relates Gibbs free energy (ΔG\Delta G) to cell potential (EE):
ΔG=−nFE\Delta G = -nFE
- Determines the spontaneity of a redox reaction.
Key Takeaways
- Faraday’s constant = 96485 C/mol.
- Represents charge carried by one mole of electrons.
- Used in electrolysis, Nernst equation, and Gibbs free energy calculations.
Let me know if you need further clarification!
Aditya Raj Anand Changed status to publish March 11, 2025